Identify acidic salts below.

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An acidic salt is formed in the reaction of neutralization between a strong acid and a weak base. For example, AlCl3 is a product of neutralization reaction between HCl and Al(OH)3. HCl is a strong acid and Al(OH)3 is a weak base. Hence, AlCl3 is an acidic salt.

Another way to look at this: an acidic salt is made of a cation, which is a weak Bronstead-Lowry acid, and an anion, which is a Bronstead-Lowry base of negligible strenth (not a base). For example, Al3+ is a weak acid. Cl- has negligible strength as a base (not a base). Hence, AlCl3 is an acidic salt.

Other common examples are NH4Cl, NH2(CH2CH3)2Br, etc.